Orbitals are used as a basis to construct wavefunction.
Can one measure a basis?
Of course not!
It is similar to the claim that one has made a tomography of the X axis.

of course the real thing is the configuration. but it seems to me that the one electron orbitals are a pretty good approximation because you are able to measure their energies with XPS and because Hartree-Fock works. therefore it makes sense to me that you can also find their shape experimentally.

I have to say that I don't really know anything about wave packet dynamics though

good to read it ....

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